2-Methyl-2-(3-nitrophenyl)-1,3-dithiane
نویسندگان
چکیده
The title compound, C(11)H(13)NO(2)S(2), contains a 1,3-dithiane ring in an almost ideal chair conformation with the following puckering parameters: Q = 0.7252 (15) Å, θ = 6.71 (13) and ϕ = 50.4 (11)°. The benzene ring occupies an axial position at the dithiane ring. The nitro group is almost coplanar with the benzene ring [O-N-C-C = -3.2 (2)°]. The mol-ecule has an L-shape with a C-C-C-C torsion angle of -74.15 (17)° for the atoms of the methyl group and the dithiane-benzene linkage. The crystal packing is stabilized only via weak non-specific van der Waals inter-actions.
منابع مشابه
2-(4-Nitrophenyl)-1,3-dithiane
The nitro group in the title compound, C(10)H(11)NO(2)S(2), is almost coplanar with the benzene ring, making a dihedral angle of 3.42 (8)°. The 1,3-dithiane ring adopts a chair conformation. The crystal structure is stabilized by inter-molecular C-H⋯O and C-H⋯π [C⋯Cg = 3.4972 (10) Å] inter-actions.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012